Published at http://www.ukerc.ac.uk/support/tiki-index.php?page_ref_id=1871

Dear All,

By way of a reply to Jeff’s short piece on Rare Earth Elements and in the hope that the UK takes a rational view on mineral supply chain policy I bring the following points to the table.

1. REEs are found at economic grades on 5 continents. We let China mine them because they have a peculiar deposit that has very little associated radioactivity. Yes, labour is cheap, but the price differential compared with, for example Australian deposits is mainly in the processing. Chinese artisinal miners can mine and partially process the ore from the Baotau deposit without worrying about the uranium and thorium minerals that come with REEs almost everywhere else in the world. We in the west don’t like to mine REEs because the come from ‘hot’ granites and we have to deal with the waste accordingly.
2. There is a credible suggestion that China has only kicked up a fuss over REEs because Greenland was equivocating over whether to allow development of its world-class mixed REE/uranium deposits.
3. REEs are not alone in being of concern to policy-makers. The wider minerals supply chain is currently being viewed through the lens of what should probably be known as The Critical Minerals Discourse. The USA, the EU, Japan and China have all put in place policy or are in the process of putting in place policy with regard to the minerals that each economic bloc feels are most critical under their own definitions. For the US supplies of minerals that it feels are necessary for military superiority are key, for the EU its economic stability but with a special reference to nuclear technologies, for Japan its metals necessary to drive its auto export industry and for China there is a real mix of developmental metals and high tech metals. The UK’s report was carried out from completely the wrong perspective and has little relevance to the global minerals trade.
4. So far the world has listed 34 minerals as ‘critical’. REEs are only one group. If there is a bubble every time a new piece of technology comes to the fore then we should prepare for many, many more bubbles. My bet for the next good bubble, on the basis of the energy technologies that I know are in the pipeline, is ruthenium. It’s a by-product of platinum processing but is currently mostly poured away with waste. Bubbles are no good for the mining industry because they inject uncertainty into future pricing. It takes 5-50 years to develop a mine and its difficult enough convincing investors to take a risk on metals prices without hyperinflation of specific products due to policy intervention or media hype. Everyone in the business knows that bad decisions get made in bubble conditions and mines funded in those times close quickly.
5. Larger miners are generally not interested in the kind of materials that are currently considered critical because the products are low volume and so relatively low profit. The smaller miners that we are relying on to bring us these critical minerals are therefore higher risk investments as they are usually undercapitalised.
6. Every report published on critical minerals in the last 10 years is wrong. The EU’s report is least wrong. They are wrong because they concentrate on the minerals critical to advanced manufacturing and not the minerals necessary to support a basic public infrastructure. This means that we have the ridiculous situation whereby food is deemed less important than magnets and shelter is seen as less critical than night-vision goggles. We have used REEs for less than 100 years. In less than 10 years they have apparently become more critical to survival than phosphates or aggregates. They are not and never will be as important to long-term human survival as fertilizer or building materials, and they will never be as important as copper is in technological terms. So please, a sense of perspective. If you really want to get into a justifiable panic do it over being able to electrify the world using copper wire, because there is a genuine risk that we will not be able to bring electricity to everyone for lack of the red metal over the next 50-100 years, but we have policies in the UK that allow or even promote disposal of large amounts of copper in preference to recycling.

A final note on the energy efficiency of metals cycles; recycling of critical minerals is underdeveloped in most cases and impossible in some due to their mode of use. REEs for example are mostly used in alloy or in mixed oxide form, so present a difficult recycling target, while other critical metals such as tungsten and cobalt are already recycled to a high degree because their uses are constrained in high value sectors and relatively pure forms. But as a sector the volumes of critical minerals are so low that energy efficiency in their supply chains is not as big a deal as it is in, for example aluminium, zinc, copper or nickel. For example, while the UK may boast a headline copper recycling figure of 80%, the vast majority of that metal recycled never makes it into product before it is shipped back to copper smelters to be re-formed into ‘virgin’ forms for re-use. So an individual copper atom may be shipped back and forth across the world 4 or 5 times before it actually gets used in a technology and the chances that it gets recycled after it has been embodied in a product is virtually nil. Only around 10% of ‘old scrap’ copper is recycled in the UK and the figure is similar across Europe once you dig through the rhetoric.

The urban mining movement has a potential economic value of over $50bn per year in copper and gold alone and yet we export end-of-life products and e-waste to China by the shipload. Contrary to received wisdom China is currently the leader in e-waste recycling, both by value and technology, and is publishing paper after paper on the automation of that process. We are their mine for this raw material and they get it at knock-down prices because we have the wrong end of the stick with regards to its value. So in my mini-polemic I plead for a rational view on minerals, their supply chains and their use. Be concerned over mineral supplies, but be concerned over those supplies that actually matter not the ones where you have a choice over whether they matter or not. Your definition of ‘critical’ minerals defines you.

Update:
A Reuters piece on the same subject

This is a repost of a piece that I wrote for MetalMiner.

Until the 1900s it wasn’t uncommon to see women working in the tin and copper mines of Cornwall. These Bal Maidens all but ran the above ground operations taking the ore from the kibbles (ore buckets) and running it through hand sorting and processing, right up to the point of smelting. A combination of legislation, geology, automation and metals prices eventually smothered the Cornish mines, but we should remember that only 100 years ago virtually all hard-rock ores were hand processed everywhere in the world.

I was amazed by the resigned comments of US recyclers that it was simply uneconomic to recycle e-waste in the US and decided to take a look at the state of the art, because as the Bal Maidens demonstrate, time and technology do move on. It turns out that China is publishing scientific paper after scientific paper on industrial scale e-waste reprocessing. Some of the techniques, such as the dissassembly of printed circuit boards using ultrasound, are already operating at industrial scale. Others, like the use of super-critical methanol or water to boil the components off circuit boards, are still in R&D. But there is a definite and conscious technological effort going on to recover as much of the metal from e-waste as economically possible. Judging by the science the Chinese are having a great time mining these new deposits and are looking forward to the forecast increase in trade.

And it is potentially a very substantial trade. The figures quoted in the NYT do not do it justice. Using some of the more conservative grades reported in peer-reviewed journals, every year 50 million tonnes of e-waste could produce as much copper as 19 Bingham Canyons (4.7 Million tonnes) and as much gold as four AngloGold Ashantis (8 Million ounces). That’s around $50bn worth of refined metal, just in copper and gold. That is not to mention the millions of ounces of silver, thousands of tonnes of aluminium, steel, tin, nickel and lead and the possible extraction of some of the more specialist metals like gallium and cobalt. A back of the envelope calculation shows that if you had all the e-waste in one spot and efficient technology to exploit it you could build a company comparable in size to Rio Tinto or BHPBilliton.

When we hear about e-waste it is usually in terms of pollution due to mercury, lead and cadmium that is vented into the environment from small artisinal workshops. What we should also remember is that it is currently economic to have an estimated 700,000 Chinese employed in informal e-waste recycling. Right now there are around 7,000 people employed in the whole recycling sector in the US, similar to the number of Bal Maidens employed in the Cornish mines in the 1850s, and they are (were) all using similar manual techniques. China has started automating e-waste recycling and cleaning up the process as it does so. What is stopping the rest of us ?

Maybe we are waiting until we have to start mining our landfills. Its not as far fetched as it sounds. London hosted the first ever landfill mining conference in 2008. Any concentration of metals should attract attention as prices rise and landfill was no exception pre-crash. With advances in bacterial leaching, as well as an existing and substantial knowledge-base in both acid and alkali hydrometallurgy the only real technical issue holding back in-situ landfill mining is the grade, which in comparison to e-waste is low.

Which provokes the final question; why would you dilute high-grade e-waste with municipal solid waste and make metals recovery more difficult and less profitable in the future ? It seems to me that by exporting the raw material we have the e-waste business upside-down and it is waiting for the same kind of revolution that the mini-mills brought for steel.

Metals in short supply ?

February 13, 2010

A program from BBC Radio 4 that looks at possible shortages in the metals supply chain.
This link will only be active until Feb 18th, sorry.

http://www.bbc.co.uk/iplayer/episode/b00qjx5q/Out_Of_This_World/

Its an OK program. It covers the basics well, the researcher obviously found the two main sides of the argument. He didn’t chase down their fundamental positions though.
He looks a new technology as a solution mainly in recycling of metals, skipped over substitution in a sentence, had some kook from Surrey Uni muddying the waters with talk about space mining phosphorous (of course you aren’t going to mine bulk commodities in space to throw down Earth’s gravity well, that’s stupid ! If you were that desperate you’d use them to farm in space and throw the products down the well. Idiot !)

The guy who seems to being interviewed in a pub is a co-author of the UK’s only public, government sponsored report that I’ve seen on this topic. The report is OK, though quite why someone would employ a consultancy that specialises in the environmental impacts of waste disposal to conduct a metals supply study is a mystery. Its a bit like employing an undertaker to speak about health issues.

The MaterialsUK group is carrying out a much fuller examination of all this including something that I advocated in my thesis on copper supply, a full materials flow analysis to find out how much of what is where in the UK’s economy. Once you know that, only then can you really start to tailor policy towards material consumption. David King was right that we must eventually get to a post-consumption economy, but there are a few steps that we must take to get there. Knowing how we consume is one of them.

A quick question; at what point did mining engineers suddenly become the people who find minerals ? As a resource geologist I must have missed that meeting ;)

Just a final word on the whole materials security discourse. This is being driven by two main movements; the anti-consumption environmental movement and the American economic/energy independence/security side of the tracks. Bit of an unholy alliance really ;) It should be recognised that the majority of pressure coming from West of the Atlantic is from the industrial/military and for those who are really interested; the US’s stance towards material security is embodied in the book “Minerals, Critical Minerals and the US Economy” . The majority of public pressure coming from Europe is from the anti-consumption angle, but economic imperatives to support high value, high-tech manufacturing in Germany and the Franco-centric nuclear industry are also important factors behind the scenes.
The flip side of the argument comes from the economists (Humphries on the program) and the materials scientists.

My own opinion is that there is no generalisation to be made here about materials running out on a global scale. Each material has a specific set of consumption pathways that it may take, each has a set of potential physical substitutes, each has a potential set of new sources, each has an availability to recycling, each technology that uses each material has its own pathway.

There is however likely to be issues over local availability as geology, politics and economics conspire to restrict efficient supply, and that really is the point. If we want to fight over ‘stuff’ we can, all we need to do is keep increasing its consumption without increasing the efficiency of its supply or recycling, human nature and politics will do the rest for us. However, since we know that conflict (physical or economic) is pretty much inevitable without concrete action to change course, do we not have an ethical responsibility to try and alter course whether it be though scientific/technological innovation or policy-led initiatives ?

The miners will mine only what they can sell, nothing other than economics is required to control that, so putting on the table products or policies that adjust consumption projections has to be the way to go.

Superconductors have been around in the labs for decades now. They have been a mainstay of high-end scientific research and niche medical applications for decades, but on the industrial scale they have always been a bit to expensive to run in mass market applications, like the energy sector. Theirs has been a story of potential energy efficiency boosts, power savings, zero transmission losses and all the first order energy system changes that no-one is against. Its time to take a look at them a little closer since I dismissed them so off-handedly in my previous post regarding the North Sea super grid.

Crash course
Superconductivity was discovered 99 years ago.
Different materials become superconductors at different temperatures.
HTS (High Temperature Super-Conductors) are defined as having a transition temperature above 30K (-243C), and the highest temp superconductors have a validated operating temperature around 135K. The boiling point of liquid nitrogen is 77K, so this has made HTS much more accessible and practical as nitrogen is commonly used as a liquified gas.
However, recently an HTS material that operates at 254K (-19C) has been claimed. This would clearly be a massive leap forward as standard compression-cycle refrigeration techniques could be used rather than immersion in liquified gas. Obviously these are lab findings and there is no guarantee that production of these materials could be scaled up to industrial quantities (they use some relatively commonplace elements, so there shouldn’t be any resource availability problems for once). The standard 10 years+ from first publication warning applies here i.e. no field application will arise from a lab discovery within 10 years of first publication.
So industrially we are looking at the 135K materials, which is still OK, but not the massive jump that we’d all like to see.

Energy Applications
Cabling – Zero transmission losses over long distances, or high capacity transmission without the current massive infrastructure (overhead pylons) are the main lures.
Power:Weight improvements – instead of copper conductors, using HTS in motors greatly increases their power:weight ratio. The applications in electric vehicles are obvious, so I won’t labour that point, but also consider all those static motors in air-conditioning units, factory assembly lines, and my personal favorite the conveyor belt. The infrastructure to hold these in place could be smaller and lighter, their maintenance quicker and safer as well as their operating costs lower.
For ‘motors’ also read ‘generators’ and you see the application for wind turbines and other renewable generating technologies. Smaller lighter nacelles means smaller lighter towers, means cheaper generating capacity and lower maintenance costs.

Renewable Energy Focus has done this two parter (Part One & Part Two) which covers all these much better than I ever could. You’ll need to subscribe for free to access the full articles, but its worth it.

The take home from these two articles is that super conductors should be on the shopping list of industry. I was too quick to dismiss them for the North Sea grid. With 150 times the carrying capacity per unit weight and 1/3 of the transmission losses superconducting cabling should be the first option for mega projects, not the last.
When/if those properly room temperature super-conductors reach the supermarket shelves a revolution will take hold.

Big Wind Movements

January 9, 2010

Round three of the UK offshore wind tender process totaled 32.2 GW of nameplate generating capacity. That’s a lorra lorra windmills and well above the expected 25GW power output. Lets be middle of the road and say for the sake of convenience that 3.22 MW turbines exist, that’d be 10,000 turbines located between 22km and 190km from the nearest landfall.

The London Array has started to hand out contracts. Nexans, the submarine cable specialist, has won the power export (windfarm to shore) cable contract. It is 100M Euro for 4x 53km long 150kV capacity copper cables to carry up to 1GW of power from 175 turbines.

If we do a quick bit of maths on that for 32 times the power, roughly twice the distance and 57 times the number of turbines, if the Round Three windfarms use the same technology as the London Array, the export cables alone should cost in the order of 6.5bn Euros (not including inflation or commodity risk). Using my previous estimation of the intensity of copper use in wind power, 10,000 offshore turbines and their associated cabling will use around 310,000 tonnes of conductor grade copper. Copper’s current price is around US$7,200 per tonne giving an embodied copper cost today of US$2.23bn. By the time these windmills get built, that figure looks cheap to me.

Perhaps that’s why the North Sea Supergrid got a bunk up the probability ladder by the nations next to the water. For an estimated one-off cost of 30bn Euro you get a ‘local’ connection, cutting the need for those expensive connections to shore and you get the ability to load balance using Norway’s hydro power excess.

If I had an extra billion or two I’d be looking at building a submarine cabling capacity right now. Not just the cable factory but the cable laying vessel and some upstream capacity in copper recycling. It’d be nice to think that we’d be at super conducting cables for this job, but at 6,000km total length and multi-GW capacity I’m not sure that the tech will be with us in time. Looks like HVDC instead, shame.

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